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Old January 15, 2013, 05:35 PM
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Rusty Rusty is offline
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Join Date: Aug 2007
Location: USA
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The 'c', when followed by 'e' or 'i' and the 'z', no matter the vowel that follows it, are pronounced like the 'th' in the English word 'thin' (IPA: /θ/) (not like the 'th' in the English word 'the' (IPA: /ð/)). This pronunciation is only found in peninsular Spanish (the Castilian spoken in Spain).
In Latin America, these two consonants are pronounced like an 's', when followed by a vowel.

This article may help answer your question more fully.

Only two languages of Spain, Castilian and Galician, have this sound and use the same two letters to represent it.
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