These are all prepositions and are, in many cases, used just like their Spanish equivalents, especially in prepositional phrases.
The only caution I give is that prepositions do not always translate one-for-one into the other language.
 
Examples:
 
I want to go 
to the store.
Quiero ir 
a la tienda.
 
What did you learn 
at school?
¿Qué aprendiste 
en la escuela?
At work, I wash dishes.
En el trabajo, frego los platos.
 
This present is 
for you.
Este regalo es 
para ti.
Thanks 
for the gift.
Gracias 
por el regalo.
 
The bird 
in the tree is singing.
El pájaro 
en el arbol canta.
The clouds 
in the sky look like sheep 
in the field.
Las nubes 
del cielo parecen ovejas 
en el campo.
 
Pon este libro 
en la mesa.
Put this book 
on the table.
 
I'm 
from Venezuela.
Soy 
de Venezuela.
Where are you 
from?
¿
De dónde eres?
 
Ojo:
Me alegro de que tú estés aquí.
I'm glad you're here.
Estoy seguro de que ...
I'm sure ...
 
Provide us some examples of your own. We'll let you know how well you're doing. 
