I can't think of an adjective that is that specific. I'm afraid you'll need to use both an adjective and a noun in the subject complement.
true friend
real friend
loyal friend
reliable, dependable
You can use these adjectives alone, but they don't necessarily express the idea that he is also a friend.
He is true. (could mean 'a true friend', but could also mean 'true to his name/wife/faith')
He is real. (could mean other things than being a dear friend)
He is loyal. (could mean that he is loyal to his company - a dog is loyal)
He is reliable.
He is dependable.
We sometimes hear "He is Johnny-on-the-spot." This can describe a true friend, ready to come to your aid or provide service, but it can also describe anyone who is eager to help others (could be a complete stranger to you before the aid is given at just the right time).
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