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I think there will be someone who will explain differences clearly, but here are some examples about the difference between them:
Es posible que la luna esté hecha de queso, pero lo dudo.
It's possible that the moon is made of cheese, but I doubt it.
Es posible que la luna no esté hecha de queso, sino de roca.
It's possible that the moon is not made of cheese, but of rock.
Yo uso una PC, pero sé usar una Mac.
I use a PC, but I can (also) use a Mac.
Yo no uso una PC, sino una Mac.
I don't use a PC, but a Mac.
Yo quería comprar un perro, pero necesita mucho cuidado.
I wanted to buy a dog, but it needs too much care.
No compré un perro, sino un pez tropical.
I didn't buy a dog, but a tropical fish.
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♪ ♫ ♪ Ain't it wonderful to be alive when the Rock'n'Roll plays... ♪ ♫ ♪
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